Compilation of thermal properties of hydrogen in its various isotopic and ortho-para modifications.

نویسندگان

  • H W WOOLLEY
  • R B SCOTT
  • F G BRICKWEDDE
چکیده

New developments in science and industry are aided by accurate knowledge of the behavior of important substances. The great abundance of chemical processes and comX pounds in which hydrogen is involved make it of particular interest. The experimental and derived data presented here for hydrogen extend over a large range of temperature. Low temperatures are required for the liquid and solid, and moderate and high temperatures occur in chemical reactions. The available thermal data for H2, HD, and D2 in solid, liquid, and gaseous states have been brought together, including the distinctive properties of ortho and para forms of H2 and D2. Some data not previously published have been added. The thermal data include thermodynamic functions for the ideal gas state, equilibrium constants, data of state, viscosity, and thermal conductivity with dependence on the pressure, vapor pressure* solid-liquid equilibria, specific heats, and latent heats. Values of state derivatives useful in thermodynamic calculations have been given for normal hydrogen, and. the related differences between thermodynamic functions for real and ideal gas states have been evaluatedA temperature entropy diagram for normal H2 in the range of experimental data is also given. The compiled thermal properties of hydrogen are presented in 38 tables, 33 graphs, and numerous equations. The sources of the data have been given in an extensive bibliography.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Design of the Reactor, Selection of Catalyst for Ortho to Para Hydrogen Conversion and Preliminary Design of Cryogenic System for its Liquefaction

Hydrogen is an unusual substance in that its molecule exists in two forms, known as ortho and para, with markedly different properties. Energy level of the ortho molecule is higher than para, therefore, the latter is employed for industrial purposes. Consequently, for a high  conversion of  ortho to para hydrogen a catalyst reactor must be employed.  Therefore, one of  the main obj...

متن کامل

QSARS OF ANTI-FUNGAL ACTIVITY OF FURAN CARBOXANILIDE DERIVATIVES AGAINST WILD AND MUTANT STRAINS OF USTILAGO MAYDIS

The structural requirements for the inhibitor activity of various furan carboxanilide derivatives against succinate dehydrogenase complex (SDC) activity in mitochondria of either wild or mutant strains of Ustilago maydis were investigated with the aid of Hansch QSAR analysis. It has been found that the inhibitor activity against both types of enzymes is best related to the ??? or ??M of th...

متن کامل

Covalent functionalization of graphene by azobenzene with molecular hydrogen bonds for long-term solar thermal storage

Reduced graphene oxide-azobenzene (RGO-AZO) hybrids were prepared via covalent functionalization for long-term solar thermal storage. Thermal barrier (ΔEa) of cis to tran reversion and thermal storage (ΔH) were improved by molecular hydrogen bonds (H-bonds) through ortho- or para-substitution of AZO. Intramolecular H-bonds thermally stabilized cis-ortho-AZO on RGO with a long-term half-life of ...

متن کامل

Separation of water into its ortho and para isomers.

Polyatomic molecules can exist as nuclear spin isomers. For example, the ortho and para hydrogen spin isomers are characterized by different values of specific heat, boiling point, heat of vapor formation, and so forth (1). Hydrogen has been the only substance whose spin modifications are well studied and available for practical use. Like H2, a water molecule also has two alternative orientatio...

متن کامل

The ortho and para fractions of molecular hydrogen in protostellar outflows and Herbig-Haro objects

Hydrogen molecules exist in two forms, according to the alignment of the nuclear spins. We present an accurate method for extracting the distributions of the two forms from three K-band infrared transitions. Images of the 1-0 S(0), S(1) and S(2) emission lines yield the ortho and para spatial distributions with negligible extinction and model dependence. The ortho-para ratio from individual poi...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Journal of research of the National Bureau of Standards

دوره 41 5  شماره 

صفحات  -

تاریخ انتشار 1948